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Buchwald-Type Ligands on Gold(I) Catalysis

  • Datos identificativos

    Identificador: imarina:6138918
    Autores:
    Zuccarello, GiuseppeZanini, MargheritaEchavarren, Antonio M.
    Resumen:
    Dialkyl biarylphosphine ligands, presented in the context of Pd-catalyzed cross-coupling reactions, have been extensively applied in gold(I) catalysis giving rise to numerous transformations and reaction pathways otherwise inaccessible under the action of other gold(I) catalysts. This review emphasizes how this privileged ligand class, as well as recent modifications on the biarylphosphine motive, have triggered the discovery of new reactivities in our research program. Finally, the introduction of chiral information on the ligand scaffold provides new solutions to challenging gold(I)-catalyzed enantioselective transformations.
  • Otros:

    Autor según el artículo: Zuccarello, Giuseppe; Zanini, Margherita; Echavarren, Antonio M.;
    Departamento: Química Analítica i Química Orgànica
    Autor/es de la URV: ECHAVARREN PABLOS, ANTONIO / Zanini, Margherita
    Palabras clave: Retro-buchner reaction Platinum Gold(i) catalysis Cyclizations Cyclization Complexes Carbenes Biarylphosphines Asymmetric catalysis Amination Alkynes Activated ketones A-c 1,6-enynes
    Resumen: Dialkyl biarylphosphine ligands, presented in the context of Pd-catalyzed cross-coupling reactions, have been extensively applied in gold(I) catalysis giving rise to numerous transformations and reaction pathways otherwise inaccessible under the action of other gold(I) catalysts. This review emphasizes how this privileged ligand class, as well as recent modifications on the biarylphosphine motive, have triggered the discovery of new reactivities in our research program. Finally, the introduction of chiral information on the ligand scaffold provides new solutions to challenging gold(I)-catalyzed enantioselective transformations.
    Áreas temáticas: Materiais General chemistry Ensino Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: antoniomaria.echavarren@urv.cat
    Identificador del autor: 0000-0002-6418-7930
    Fecha de alta del registro: 2024-01-13
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://onlinelibrary.wiley.com/doi/full/10.1002/ijch.201900179
    Referencia al articulo segun fuente origial: Israel Journal Of Chemistry. 60 (3-4): 360-372
    Referencia de l'ítem segons les normes APA: Zuccarello, Giuseppe; Zanini, Margherita; Echavarren, Antonio M.; (2020). Buchwald-Type Ligands on Gold(I) Catalysis. Israel Journal Of Chemistry, 60(3-4), 360-372. DOI: 10.1002/ijch.201900179
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    DOI del artículo: 10.1002/ijch.201900179
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2020
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Retro-buchner reaction
    Platinum
    Gold(i) catalysis
    Cyclizations
    Cyclization
    Complexes
    Carbenes
    Biarylphosphines
    Asymmetric catalysis
    Amination
    Alkynes
    Activated ketones
    A-c
    1,6-enynes
    Materiais
    General chemistry
    Ensino
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Astronomia / física
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