e-ISSN: 1867-3899
Código de proyecto: CTQ2016-75016-R
Palabras clave: Sustainable conversion Supported organocatalyst Reduced graphene oxides (rgo) Reduced graphene oxide Recoverability Organocatalysts Organic carbonates Nanotubes N-heterocyclic carbenes Metal-complexes Interactions Imidazolium salt Imidazolium carboxylates Heterogeneous catalysis Graphene oxide Graphene Dioxide Cycloaddition reaction Cycloaddition Cyclic carbonates Catalytic system Catalysts Carboxylation Carbon nanotubes Carbon materials Carbon material Carbon dioxide conversion Carbon dioxide Carbon beads Aromatic-compounds π ? interactions
Fecha de alta del registro: 2024-07-27
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Chemcatchem. 13 (7): 1706-1710
Referencia de l'ítem segons les normes APA: Souleymanou, Myriam Y.; El-Ouahabi, Fatima; Masdeu-Bulto, Anna M.; Godard, Cyril; (2021). Cooperative NHC-based Catalytic System Immobilised onto Carbon Materials for the Cycloaddition of CO2 to Epoxides. Chemcatchem, 13(7), 1706-1710. DOI: 10.1002/cctc.202001816
Acrónimo: ECO2VALCAT
Tipo de publicación: Journal Publications
Autor según el artículo: Souleymanou, Myriam Y.; El-Ouahabi, Fatima; Masdeu-Bulto, Anna M.; Godard, Cyril;
Departamento: Química Física i Inorgànica
Autor/es de la URV: Godard, Cyril / Masdeu Bultó, Anna Maria / SOULEYMANOU, MYRIAM YASMINE
Resumen: New pyrene-tagged imidazolium salts and their corresponding carboxylates were synthesised and the latter tested as organocatalysts in the cycloaddition of CO2 with epoxides. The best performing organocatalyst was then non-covalently immobilised onto carbon materials (carbon nanotubes (CNTs), reduced graphene oxide (rGO) and carbon beads (CBs)) via pi-pi stacking interactions and their activity and recoverability in the cycloaddition reaction were studied. The heterogenised catalyst onto reduced graphene oxide (4 a@rGO) was recycled several times although a loss of activity was observed. This catalyst was also used for the transformation of a series of epoxides under mild conditions.
Áreas temáticas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1867-3880
Direcció de correo del autor: cyril.godard@urv.cat annamaria.masdeu@urv.cat
Identificador del autor: 0000-0001-5762-4904 0000-0001-7938-3902
Enlace a la fuente original: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cctc.202001816
Programa de financiación: PROGRAMA ESTATAL DE INVESTIGACIÓN, DESARROLLO E INNOVACIÓN ORIENTADA A LOS RETOS DE LA SOCIEDAD
DOI del artículo: 10.1002/cctc.202001816
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2021
Acción del progama de financiación: VALORIZACION EFICIENTE DE CO2 A COMBUSTIBLES Y COMPUESTOS DE ALTO VALOR AÑADIDO MEDIANTE CATALISIS HOMOGENEA Y NANO-CATALISIS
Repositori URV