Autor según el artículo: Yue, Wen-Jun; Day, Craig S.; Martin, Ruben;
Departamento: Química Analítica i Química Orgànica
Autor/es de la URV: Day, Craig
Palabras clave: Site selectivity Site selective Secondary amides Saturated hydrocarbons Functionalization Bond activation Amides Alkylation
Resumen: A site-selective defluorinative sp(3) C-H alkylation of secondary amides that rapidly and reliably incorporates gemdifluoroalkene motifs into previously unfunctionalized sp(3) sites is disclosed. This protocol is distinguished by its mild conditions, wide scope, and exquisite site-selectivity, thus unlocking a new platform to introduce carbonyl isosteres at saturated hydrocarbon sites.
Áreas temáticas: Química Materiais Interdisciplinar General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Colloid and surface chemistry Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biochemistry Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: craig.day@estudiants.urv.cat
Identificador del autor: 0000-0002-6931-0280
Fecha de alta del registro: 2024-07-27
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Journal Of The American Chemical Society. 143 (17): 6395-6400
Referencia de l'ítem segons les normes APA: Yue, Wen-Jun; Day, Craig S.; Martin, Ruben; (2021). Site-Selective Defluorinative sp(3) C-H Alkylation of Secondary Amides. Journal Of The American Chemical Society, 143(17), 6395-6400. DOI: 10.1021/jacs.1c03126
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2021
Tipo de publicación: Journal Publications
Repositori URV