Articles producció científica> Química Física i Inorgànica

Th@D-5h(6)-C-80: a highly symmetric fullerene cage stabilized by a single metal ion

  • Datos identificativos

    Identificador: imarina:9218763
    Handle: https://hdl.handle.net/20.500.11797/imarina9218763
    Autores:
    Yan, YingjingMorales-Martinez, RoserZhuang, JiaxinYao, Yang-RongLi, XiaomengPoblet, Josep MRodriguez-Fortea, AntonioChen, Ning
    Resumen:
    A novel endohedral metallofullerene (mono-EMF), Th@D-5h(6)-C-80, has been successfully synthesized and fully characterized by mass spectrometry, single crystal X-ray diffraction, UV-vis-NIR and Raman spectroscopy and cyclic voltammetry. Single crystal XRD analysis unambiguously assigned the fullerene cage as D-5h(6)-C-80, the first example in which the highly symmetric cage is stabilized by a single metal ion. The combined experimental and theoretical studies further reveal that the D-5h(6)-C-80 cage, known only for its stabilization by 6-electron transfer, is stabilized by the 4-electron transfer from the encapsulated Th ion for the first time.

  • Otros:

    Autor según el artículo: Yan, Yingjing; Morales-Martinez, Roser; Zhuang, Jiaxin; Yao, Yang-Rong; Li, Xiaomeng; Poblet, Josep M; Rodriguez-Fortea, Antonio; Chen, Ning
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Morales Martínez, Roser / Poblet Rius, Josep Maria / Rodríguez Fortea, Antonio
    Palabras clave: Uv-vis nir Thorium metallography Theoretical study Single crystals Single crystal xrd Single crystal x-ray diffraction Sc3n-at-c-80 Metals Metal ions Mass spectrometry Isomer Fullerenes Fullerene cages Endohedral metallofullerenes Cyclic voltammetry Cluster Cages (mine hoists)
    Resumen: A novel endohedral metallofullerene (mono-EMF), Th@D-5h(6)-C-80, has been successfully synthesized and fully characterized by mass spectrometry, single crystal X-ray diffraction, UV-vis-NIR and Raman spectroscopy and cyclic voltammetry. Single crystal XRD analysis unambiguously assigned the fullerene cage as D-5h(6)-C-80, the first example in which the highly symmetric cage is stabilized by a single metal ion. The combined experimental and theoretical studies further reveal that the D-5h(6)-C-80 cage, known only for its stabilization by 6-electron transfer, is stabilized by the 4-electron transfer from the encapsulated Th ion for the first time.
    Áreas temáticas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: josepmaria.poblet@urv.cat antonio.rodriguezf@urv.cat
    Identificador del autor: 0000-0002-4533-0623 0000-0001-5884-5629
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
    Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d1cc02339j
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Chemical Communications. 57 (54): 6624-6627
    Referencia de l'ítem segons les normes APA: Yan, Yingjing; Morales-Martinez, Roser; Zhuang, Jiaxin; Yao, Yang-Rong; Li, Xiaomeng; Poblet, Josep M; Rodriguez-Fortea, Antonio; Chen, Ning (2021). Th@D-5h(6)-C-80: a highly symmetric fullerene cage stabilized by a single metal ion. Chemical Communications, 57(54), 6624-6627. DOI: 10.1039/d1cc02339j
    DOI del artículo: 10.1039/d1cc02339j
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2021
    Tipo de publicación: Journal Publications

  • Palabras clave:

    Catalysis,Ceramics and Composites,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Electronic, Optical and Magnetic Materials,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films
    Uv-vis nir
    Thorium metallography
    Theoretical study
    Single crystals
    Single crystal xrd
    Single crystal x-ray diffraction
    Sc3n-at-c-80
    Metals
    Metal ions
    Mass spectrometry
    Isomer
    Fullerenes
    Fullerene cages
    Endohedral metallofullerenes
    Cyclic voltammetry
    Cluster
    Cages (mine hoists)
    Surfaces, coatings and films
    Química
    Metals and alloys
    Medicina ii
    Medicina i
    Materials chemistry
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Electronic, optical and magnetic materials
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Ceramics and composites
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física

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