Autor según el artículo: Fu, Yandi; Pessagno, Federica; Manesiotis, Panagiotis; Borrull, Francesc; Fontanals, Nuria; Maria Marce, Rosa
Departamento: Química Analítica i Química Orgànica
Autor/es de la URV: Borrull Ballarín, Francesc / Fontanals Torroja, Núria / Fu, Yandi / Marcé Recasens, Rosa Maria
Palabras clave: Waste-water Synthetic cathinones Solid-phase extraction Resolution Psychoactive substances Molecularly imprinted polymer Mass-spectrometry Liquid-chromatography Ephedrine Environmental water Enantiomeric determination Cathinones Amphetamine (-)-ephedrine
Resumen: In this study, a series of molecularly imprinted polymers (MIPs) were synthesised using (1R,2S)-(-)-ephedrine or (15,2S)-(+)-pseudoephedrine as template, methacrylic acid as functional monomer and ethylene glycol dimethacrylate as cross-linking agent. A highly selective and sensitive method using the best performing MIP as sorbent in the solid-phase extraction (SPE) followed by liquid chromatography-high resolution mass spectrometry was established for the enantiomeric determination of five cathinones in river water samples. The SPE parameters (sample loading volume and pH, washing and elution solutions) were optimised so that recoveries and selectivities for the analytes were high. The enantioselectivity of MIPs towards the enantiomers of the analytes during the SPE process was also investigated. Under optimal conditions, the method developed provided satisfactory recoveries ranging from 67.6 to 83.2 % with a negligible matrix effect ranging from -5.5 to 1.8 %. The detection limits ranged from 0.3 to 0.8 ng/L and quantification limits ranged from 1.0 to 2.0 ng/L. The application of the method to the analysis of the river water samples indicated that methedmne and butylone were present at low concentration levels in river water samples.
Áreas temáticas: Spectroscopy Saúde coletiva Química Odontología Nutrição Medicina ii Medicina i Materiais Interdisciplinar Geociências Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Enfermagem Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, analytical Biotecnología Biodiversidade Astronomia / física Analytical chemistry Administração pública e de empresas, ciências contábeis e turismo
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: yandi.fu@estudiants.urv.cat nuria.fontanals@urv.cat nuria.fontanals@urv.cat rosamaria.marce@urv.cat francesc.borrull@urv.cat
Identificador del autor: 0000-0002-7534-1964 0000-0002-7534-1964 0000-0002-5667-2899 0000-0003-2718-9336
Fecha de alta del registro: 2024-10-12
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://www.sciencedirect.com/science/article/pii/S0026265X21011863?via%3Dihub
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Microchemical Journal. 175 107100-
Referencia de l'ítem segons les normes APA: Fu, Yandi; Pessagno, Federica; Manesiotis, Panagiotis; Borrull, Francesc; Fontanals, Nuria; Maria Marce, Rosa (2022). Preparation and evaluation of molecularly imprinted polymers as selective SPE sorbents for the determination of cathinones in river water. Microchemical Journal, 175(), 107100-. DOI: 10.1016/j.microc.2021.107100
DOI del artículo: 10.1016/j.microc.2021.107100
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2022
Tipo de publicación: Journal Publications
Repositori URV