Articles producció científica> Química Analítica i Química Orgànica

Valorization of Lactate Esters and Amides into Value-Added Biobased (Meth)acrylic Polymers

  • Datos identificativos

    Identificador: imarina:9380943
    Autores:
    Pala, MarcLligadas, GerardMoreno, Adrian
    Resumen:
    (Meth)acrylic polymers are massively produced due to their inherently attractive properties. However, the vast majority of these polymers are derived from fossil resources, which is not aligned with the tendency to reduce gas emissions. In this context, (meth)acrylic polymers derived from biomass (biobased polymers) are gaining momentum, as their application in different areas can not only stand the comparison but even surpass, in some cases, the performance of petroleum-derived ones. In this review, we highlight the design and synthesis of (meth)acrylic polymers derived from lactate esters (LEs) and lactate amides (LAs), both derived from lactic acid. While biobased polymers have been widely studied and reviewed, the poly(meth)acrylates with pendant LE and LA moieties evolved slowly until recently when significant achievements have been made. Hence, constraints and opportunities arising from previous research in this area are presented, focusing on the synthesis of well-defined polymers for the preparation of advanced materials.
  • Otros:

    Autor según el artículo: Pala, Marc; Lligadas, Gerard; Moreno, Adrian
    Departamento: Química Analítica i Química Orgànica
    Autor/es de la URV: Lligadas Puig, Gerard / Moreno Guerra, Adrian / PALÀ SÁNCHEZ, MARC
    Palabras clave: Tunable lcst Raft polymerization Polymers Platform Mechanical-properties Living radical polymerization Lignocellulosic biomass Ligni Lactic-acid Lactic acid Green solvent Ethyl lactate Esters Amides
    Resumen: (Meth)acrylic polymers are massively produced due to their inherently attractive properties. However, the vast majority of these polymers are derived from fossil resources, which is not aligned with the tendency to reduce gas emissions. In this context, (meth)acrylic polymers derived from biomass (biobased polymers) are gaining momentum, as their application in different areas can not only stand the comparison but even surpass, in some cases, the performance of petroleum-derived ones. In this review, we highlight the design and synthesis of (meth)acrylic polymers derived from lactate esters (LEs) and lactate amides (LAs), both derived from lactic acid. While biobased polymers have been widely studied and reviewed, the poly(meth)acrylates with pendant LE and LA moieties evolved slowly until recently when significant achievements have been made. Hence, constraints and opportunities arising from previous research in this area are presented, focusing on the synthesis of well-defined polymers for the preparation of advanced materials.
    Áreas temáticas: Química Polymers and plastics Polymer science Medicina ii Materials chemistry Materiais Interdisciplinar Farmacia Engenharias iv Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, organic Biotecnología Biomaterials Bioengineering Biochemistry & molecular biology Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: adrian.moreno@urv.cat marc.pala@estudiants.urv.cat gerard.lligadas@urv.cat
    Identificador del autor: 0000-0002-8519-1840
    Fecha de alta del registro: 2025-02-18
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Biomacromolecules. 25 (10): 6338-6356
    Referencia de l'ítem segons les normes APA: Pala, Marc; Lligadas, Gerard; Moreno, Adrian (2024). Valorization of Lactate Esters and Amides into Value-Added Biobased (Meth)acrylic Polymers. Biomacromolecules, 25(10), 6338-6356. DOI: 10.1021/acs.biomac.4c00891
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2024
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Biochemistry & Molecular Biology,Bioengineering,Biomaterials,Chemistry, Organic,Materials Chemistry,Polymer Science,Polymers and Plastics
    Tunable lcst
    Raft polymerization
    Polymers
    Platform
    Mechanical-properties
    Living radical polymerization
    Lignocellulosic biomass
    Ligni
    Lactic-acid
    Lactic acid
    Green solvent
    Ethyl lactate
    Esters
    Amides
    Química
    Polymers and plastics
    Polymer science
    Medicina ii
    Materials chemistry
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias iv
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, organic
    Biotecnología
    Biomaterials
    Bioengineering
    Biochemistry & molecular biology
    Astronomia / física
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