Autor según el artículo: Palà M; Lligadas G; Moreno A
Departamento: Química Analítica i Química Orgànica
Autor/es de la URV: Lligadas Puig, Gerard / Moreno Guerra, Adrian / Moreno Ribas, Antonio / PALÀ SÁNCHEZ, MARC
Palabras clave: Ethyl lactate Green solvent Lactic-acid Ligni Lignocellulosic biomass Living radical polymerization Mechanical-properties Platform Raft polymerization Tunable lcst
Resumen: (Meth)acrylic polymers are massively produced due to their inherently attractive properties. However, the vast majority of these polymers are derived from fossil resources, which is not aligned with the tendency to reduce gas emissions. In this context, (meth)acrylic polymers derived from biomass (biobased polymers) are gaining momentum, as their application in different areas can not only stand the comparison but even surpass, in some cases, the performance of petroleum-derived ones. In this review, we highlight the design and synthesis of (meth)acrylic polymers derived from lactate esters (LEs) and lactate amides (LAs), both derived from lactic acid. While biobased polymers have been widely studied and reviewed, the poly(meth)acrylates with pendant LE and LA moieties evolved slowly until recently when significant achievements have been made. Hence, constraints and opportunities arising from previous research in this area are presented, focusing on the synthesis of well-defined polymers for the preparation of advanced materials.
Áreas temáticas: Astronomia / física Biochemistry & molecular biology Bioengineering Biomaterials Biotecnología Chemistry, organic Ciência de alimentos Ciências agrárias i Ciências biológicas i Ciências biológicas ii Ciências biológicas iii Engenharias ii Engenharias iv Farmacia Interdisciplinar Materiais Materials chemistry Medicina ii Polymer science Polymers and plastics Química
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: gerard.lligadas@urv.cat antonio.moreno@urv.cat marc.pala@urv.cat adrian.moreno@urv.cat marc.pala@urv.cat
Identificador del autor: 0000-0002-8519-1840 0000-0003-3945-2314
Fecha de alta del registro: 2024-10-26
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://pubs.acs.org/doi/10.1021/acs.biomac.4c00891
Referencia al articulo segun fuente origial: Biomacromolecules. 25 (10): 6338-6356
Referencia de l'ítem segons les normes APA: Palà M; Lligadas G; Moreno A (2024). Valorization of Lactate Esters and Amides into Value-Added Biobased (Meth)acrylic Polymers. Biomacromolecules, 25(10), 6338-6356. DOI: 10.1021/acs.biomac.4c00891
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
DOI del artículo: 10.1021/acs.biomac.4c00891
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2024
Tipo de publicación: Journal Publications
Repositori URV