Articles producció científica> Química Analítica i Química Orgànica

Valorization of Lactate Esters and Amides into Value-Added Biobased (Meth)acrylic Polymers

  • Datos identificativos

    Identificador: imarina:9380943
    Autores:
    Palà MLligadas GMoreno A
    Resumen:
    (Meth)acrylic polymers are massively produced due to their inherently attractive properties. However, the vast majority of these polymers are derived from fossil resources, which is not aligned with the tendency to reduce gas emissions. In this context, (meth)acrylic polymers derived from biomass (biobased polymers) are gaining momentum, as their application in different areas can not only stand the comparison but even surpass, in some cases, the performance of petroleum-derived ones. In this review, we highlight the design and synthesis of (meth)acrylic polymers derived from lactate esters (LEs) and lactate amides (LAs), both derived from lactic acid. While biobased polymers have been widely studied and reviewed, the poly(meth)acrylates with pendant LE and LA moieties evolved slowly until recently when significant achievements have been made. Hence, constraints and opportunities arising from previous research in this area are presented, focusing on the synthesis of well-defined polymers for the preparation of advanced materials.
  • Otros:

    Autor según el artículo: Palà M; Lligadas G; Moreno A
    Departamento: Química Analítica i Química Orgànica
    Autor/es de la URV: Lligadas Puig, Gerard / Moreno Guerra, Adrian / Moreno Ribas, Antonio / PALÀ SÁNCHEZ, MARC
    Palabras clave: Ethyl lactate Green solvent Lactic-acid Ligni Lignocellulosic biomass Living radical polymerization Mechanical-properties Platform Raft polymerization Tunable lcst
    Resumen: (Meth)acrylic polymers are massively produced due to their inherently attractive properties. However, the vast majority of these polymers are derived from fossil resources, which is not aligned with the tendency to reduce gas emissions. In this context, (meth)acrylic polymers derived from biomass (biobased polymers) are gaining momentum, as their application in different areas can not only stand the comparison but even surpass, in some cases, the performance of petroleum-derived ones. In this review, we highlight the design and synthesis of (meth)acrylic polymers derived from lactate esters (LEs) and lactate amides (LAs), both derived from lactic acid. While biobased polymers have been widely studied and reviewed, the poly(meth)acrylates with pendant LE and LA moieties evolved slowly until recently when significant achievements have been made. Hence, constraints and opportunities arising from previous research in this area are presented, focusing on the synthesis of well-defined polymers for the preparation of advanced materials.
    Áreas temáticas: Astronomia / física Biochemistry & molecular biology Bioengineering Biomaterials Biotecnología Chemistry, organic Ciência de alimentos Ciências agrárias i Ciências biológicas i Ciências biológicas ii Ciências biológicas iii Engenharias ii Engenharias iv Farmacia Interdisciplinar Materiais Materials chemistry Medicina ii Polymer science Polymers and plastics Química
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Direcció de correo del autor: gerard.lligadas@urv.cat antonio.moreno@urv.cat marc.pala@urv.cat adrian.moreno@urv.cat marc.pala@urv.cat
    Identificador del autor: 0000-0002-8519-1840 0000-0003-3945-2314
    Fecha de alta del registro: 2024-10-26
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Referencia al articulo segun fuente origial: Biomacromolecules. 25 (10): 6338-6356
    Referencia de l'ítem segons les normes APA: Palà M; Lligadas G; Moreno A (2024). Valorization of Lactate Esters and Amides into Value-Added Biobased (Meth)acrylic Polymers. Biomacromolecules, 25(10), 6338-6356. DOI: 10.1021/acs.biomac.4c00891
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2024
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Biochemistry & Molecular Biology,Bioengineering,Biomaterials,Chemistry, Organic,Materials Chemistry,Polymer Science,Polymers and Plastics
    Ethyl lactate
    Green solvent
    Lactic-acid
    Ligni
    Lignocellulosic biomass
    Living radical polymerization
    Mechanical-properties
    Platform
    Raft polymerization
    Tunable lcst
    Astronomia / física
    Biochemistry & molecular biology
    Bioengineering
    Biomaterials
    Biotecnología
    Chemistry, organic
    Ciência de alimentos
    Ciências agrárias i
    Ciências biológicas i
    Ciências biológicas ii
    Ciências biológicas iii
    Engenharias ii
    Engenharias iv
    Farmacia
    Interdisciplinar
    Materiais
    Materials chemistry
    Medicina ii
    Polymer science
    Polymers and plastics
    Química
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