Tesis doctorals> Departament de Química

The activation of diboron reagents and their application in catalytic boron additions to alkenes

  • Datos identificativos

    Identificador: TDX:1044
    Autores:
    Bonet Laplana, Amadeu
    Resumen:
    Organoborane compounds are highly used in a huge number of fields, from medicine, in the boron neutral capture therapy or other molecules with biological activity to the use of functional molecules such us polymers. In our case, we focused our atention in the use of organoborane compounds as a intermediates for the synthesis of high value products. The main topic of this thesis is develop new synthetic methodologies for the efficient obtaition of organoborane compounds. We focus in the synthesis of -boryl carbonyl compounds as a synthons for the synthesis of difuncional molecules. We studied the boron addition to unsaturated molecules in to main strategies: the boron addition using transition metal catalyst or without metal. Always with special attention for the chiral approach of the reaction.
  • Otros:

    Fecha: 2012-03-02
    Departamento/Instituto: Departament de Química Física i Inorgànica Universitat Rovira i Virgili.
    Idioma: eng
    Identificador: http://hdl.handle.net/10803/79130
    Fuente: TDX (Tesis Doctorals en Xarxa)
    Autor: Bonet Laplana, Amadeu
    Director: Fernández Gutiérrez, Mª Elena Gulyàs, Henrik
    Formato: application/pdf 244 p.
    Editor: Universitat Rovira i Virgili
    Palabra clave: Diboration Boron addition B-boration Catalysis Organoborane Boron
    Título: The activation of diboron reagents and their application in catalytic boron additions to alkenes
    Materia: 547 - Química orgànica 546 - Química inorgànica 54 - Química
  • Palabras clave:

    547 - Química orgànica
    546 - Química inorgànica
    54 - Química
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