Treballs Fi de GrauQuímica Física i Inorgànica

Zn catalysts for the reaction of cycloadition of CO2 and epoxides

  • Identification data

    Identifier:  TFG:1204
    Authors:  Roig Frató, Natàlia
    Abstract:
    A new zinc complexes with N4-donor macrociclic ligands has been prepared and characterized. We report also the synthesis optimization of a complex based on stable and easy-to-handle 2,9-bis(imino)-1,10-phenanthronyl ligands. These complexes are active catalysts for the cycloaddition of CO2 and 1,2-epoxyhexane, affording epoxide conversions up to 94 % with yields up to 66 %.
  • Others:

    Department: Química Física i Inorgànica
    TFG credits: 12
    Subject: Química
    Work's public defense date: 2016-06-17
    Creation date in repository: 2017-06-02
    Academic year: 2015-2016
    Student: Roig Frató, Natàlia
    Access rights: info:eu-repo/semantics/openAccess
    Education area(s): Química
    Entity: Universitat Rovira i Virgili (URV)
    Confidenciality: No
    Project director: Masdeu Bultó, Anna Maria
    Language: cat
  • Keywords:

    catalysts
    carbon dioxide
    synthesis
    Chemistry
  • Documents:

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