Autor segons l'article: Cuenca, Ana B; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena
Departament: Química Física i Inorgànica
Autor/s de la URV: Fernández Gutiérrez, Maria Elena / Fernández López, Elena
Paraules clau: Unsaturated-compounds Transition-metal-free b-b Terminal alkynes N-heterocyclic carbenes Iminium ion generators Free borylation Diboron tetrachloride Catalyzed diboration Boron conjugate addition Bond formation Acyclic alpha,beta-unsaturated carbonyls Activation modes
Resum: This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of B-B and B-interelement bonds, as well as the generation of new C-B and C-interelement bonds, in a selective way. The greener consequences of these novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidence that supports the innovative theories are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field.
Àrees temàtiques: Química Materiais General medicine General chemistry Ciências biológicas ii Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Antropologia / arqueologia
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 14604744
Adreça de correu electrònic de l'autor: mariaelena.fernandez@urv.cat
Identificador de l'autor: 0000-0001-9025-1791
Data d'alta del registre: 2024-11-09
Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
Enllaç font original: https://pubs.rsc.org/en/content/articlelanding/2017/cs/c6cs00692b#!divAbstract
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Chemical Society Reviews. 46 (2): 415-430
Referència de l'ítem segons les normes APA: Cuenca, Ana B; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena (2017). Transition-metal-free B-B and B-interelement reactions with organic molecules. Chemical Society Reviews, 46(2), 415-430. DOI: 10.1039/c6cs00692b
DOI de l'article: 10.1039/c6cs00692b
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2017
Tipus de publicació: Journal Publications
Repositori URV