Articles producció científica> Química Física i Inorgànica

Transition-metal-free B-B and B-interelement reactions with organic molecules

  • Datos identificativos

    Identificador: imarina:2794970
    Handle: http://hdl.handle.net/20.500.11797/imarina2794970
  • Autores:

    Cuenca, Ana B.
    Shishido, Ryosuke
    Ito, Hajime
    Fernandez, Elena
  • Otros:

    Autor según el artículo: Cuenca, Ana B.; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena;
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Fernández Gutiérrez, Maria Elena
    Palabras clave: Unsaturated-compounds Transition-metal-free b-b Terminal alkynes N-heterocyclic carbenes Iminium ion generators Free borylation Diboron tetrachloride Catalyzed diboration Boron conjugate addition Bond formation Acyclic alpha,beta-unsaturated carbonyls Activation modes
    Resumen: This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of B-B and B-interelement bonds, as well as the generation of new C-B and C-interelement bonds, in a selective way. The greener consequences of these novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidence that supports the innovative theories are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field.
    Áreas temáticas: Química Materiais General medicine General chemistry Ciências biológicas ii Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Antropologia / arqueologia
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 14604744
    Direcció de correo del autor: mariaelena.fernandez@urv.cat
    Identificador del autor: 0000-0001-9025-1791
    Fecha de alta del registro: 2023-02-18
    Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
    Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2017/cs/c6cs00692b#!divAbstract
    URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Chemical Society Reviews. 46 (2): 415-430
    Referencia de l'ítem segons les normes APA: Cuenca, Ana B.; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena; (2017). Transition-metal-free B-B and B-interelement reactions with organic molecules. Chemical Society Reviews, 46(2), 415-430. DOI: 10.1039/c6cs00692b
    DOI del artículo: 10.1039/c6cs00692b
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2017
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary
    Unsaturated-compounds
    Transition-metal-free b-b
    Terminal alkynes
    N-heterocyclic carbenes
    Iminium ion generators
    Free borylation
    Diboron tetrachloride
    Catalyzed diboration
    Boron conjugate addition
    Bond formation
    Acyclic alpha,beta-unsaturated carbonyls
    Activation modes
    Química
    Materiais
    General medicine
    General chemistry
    Ciências biológicas ii
    Ciência de alimentos
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Antropologia / arqueologia
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