Autor según el artículo: Cuenca, Ana B; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena
Departamento: Química Física i Inorgànica
Autor/es de la URV: Fernández Gutiérrez, Maria Elena / Fernández López, Elena
Palabras clave: Unsaturated-compounds Transition-metal-free b-b Terminal alkynes N-heterocyclic carbenes Iminium ion generators Free borylation Diboron tetrachloride Catalyzed diboration Boron conjugate addition Bond formation Acyclic alpha,beta-unsaturated carbonyls Activation modes
Resumen: This review is a guided tour along the activation modes and reactivity of B-B, B-Si, B-N, B-S, B-Se and B-P reagents, in the absence of any transition metal complex. Here are disclosed the general concepts related to the homolytic and heterolytic cleavage of B-B and B-interelement bonds, as well as the generation of new C-B and C-interelement bonds, in a selective way. The greener consequences of these novel routes facilitate the gram scale preparations of target functionalised organic compounds. Intrinsic data about the suggested mechanisms and spectroscopic evidence that supports the innovative theories are provided along the review. Since this is a stimulating area of work that has emerged within the last decade, this overview serves as the basis to understand the new trends and hopefully to generate inspiration for future discoveries in the field.
Áreas temáticas: Química Materiais General medicine General chemistry Ciências biológicas ii Ciência de alimentos Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Antropologia / arqueologia
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 14604744
Direcció de correo del autor: mariaelena.fernandez@urv.cat
Identificador del autor: 0000-0001-9025-1791
Fecha de alta del registro: 2024-11-09
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2017/cs/c6cs00692b#!divAbstract
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Chemical Society Reviews. 46 (2): 415-430
Referencia de l'ítem segons les normes APA: Cuenca, Ana B; Shishido, Ryosuke; Ito, Hajime; Fernandez, Elena (2017). Transition-metal-free B-B and B-interelement reactions with organic molecules. Chemical Society Reviews, 46(2), 415-430. DOI: 10.1039/c6cs00692b
DOI del artículo: 10.1039/c6cs00692b
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2017
Tipo de publicación: Journal Publications
Repositori URV