Articles producció científica> Química Física i Inorgànica

Metal‐Free Synthesis of N‐Aryl Amides using Organocatalytic Ring‐Opening Aminolysis of Lactones

  • Dades identificatives

    Identificador: imarina:5131443
    Autors:
    Guo, WushengGomez, Jose EnriqueMartinez-Rodriguez, LuisBandeira, Nuno A. G.Bo, CarlesKleij, Arjan W.
    Resum:
    Catalytic ring-opening of bio-sourced non-strained lactones with aromatic amines can offer a straightforward, 100% atom-economical, and sustainable pathway towards relevant N-aryl amide scaffolds. Herein, the first general, metal-free, and highly efficient N-aryl amide formation is reported from poorly reactive aromatic amines and non-strained lactones under mild operating conditions using an organic bicyclic guanidine catalyst. This protocol has high application potential as exemplified by the formal syntheses of drug-relevant molecules.
  • Altres:

    Autor segons l'article: Guo, Wusheng; Gomez, Jose Enrique; Martinez-Rodriguez, Luis; Bandeira, Nuno A. G.; Bo, Carles; Kleij, Arjan W.;
    Departament: Química Física i Inorgànica
    Autor/s de la URV: Bo Jané, Carles
    Paraules clau: Ring-opening aminolysis Organocatalysis N-aryl amides Lactones Aromatic amines organocatalysis n-aryl amides lactones aromatic amines
    Resum: Catalytic ring-opening of bio-sourced non-strained lactones with aromatic amines can offer a straightforward, 100% atom-economical, and sustainable pathway towards relevant N-aryl amide scaffolds. Herein, the first general, metal-free, and highly efficient N-aryl amide formation is reported from poorly reactive aromatic amines and non-strained lactones under mild operating conditions using an organic bicyclic guanidine catalyst. This protocol has high application potential as exemplified by the formal syntheses of drug-relevant molecules.
    Àrees temàtiques: Química Materials science (miscellaneous) Materials science (all) Materiais Interdisciplinar Green & sustainable science & technology General materials science General energy General chemical engineering Farmacia Environmental chemistry Engenharias iii Engenharias ii Energy (miscellaneous) Energy (all) Chemistry, multidisciplinary Chemical engineering (miscellaneous) Chemical engineering (all) Biotecnología Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: carles.bo@urv.cat
    Identificador de l'autor: 0000-0001-9581-2922
    Data d'alta del registre: 2024-09-07
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.201700415
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Chemsuschem. 10 (9): 1969-1975
    Referència de l'ítem segons les normes APA: Guo, Wusheng; Gomez, Jose Enrique; Martinez-Rodriguez, Luis; Bandeira, Nuno A. G.; Bo, Carles; Kleij, Arjan W.; (2017). Metal‐Free Synthesis of N‐Aryl Amides using Organocatalytic Ring‐Opening Aminolysis of Lactones. Chemsuschem, 10(9), 1969-1975. DOI: 10.1002/cssc.201700415
    DOI de l'article: 10.1002/cssc.201700415
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2017
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Chemical Engineering (Miscellaneous),Chemistry, Multidisciplinary,Energy (Miscellaneous),Environmental Chemistry,Green & Sustainable Science & Technology,Materials Science (Miscellaneous)
    Ring-opening aminolysis
    Organocatalysis
    N-aryl amides
    Lactones
    Aromatic amines
    organocatalysis
    n-aryl amides
    lactones
    aromatic amines
    Química
    Materials science (miscellaneous)
    Materials science (all)
    Materiais
    Interdisciplinar
    Green & sustainable science & technology
    General materials science
    General energy
    General chemical engineering
    Farmacia
    Environmental chemistry
    Engenharias iii
    Engenharias ii
    Energy (miscellaneous)
    Energy (all)
    Chemistry, multidisciplinary
    Chemical engineering (miscellaneous)
    Chemical engineering (all)
    Biotecnología
    Astronomia / física
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