Autor segons l'article: Guo, Wusheng; Gomez, Jose Enrique; Martinez-Rodriguez, Luis; Bandeira, Nuno A G; Bo, Carles; Kleij, Arjan W
Departament: Química Física i Inorgànica
Autor/s de la URV: Bo Jané, Carles
Paraules clau: Ring-opening aminolysis; Organocatalysis; N-aryl amides; Lactones; Aromatic amines; organocatalysis; n-aryl amides; lactones; aromatic amines
Resum: Catalytic ring-opening of bio-sourced non-strained lactones with aromatic amines can offer a straightforward, 100% atom-economical, and sustainable pathway towards relevant N-aryl amide scaffolds. Herein, the first general, metal-free, and highly efficient N-aryl amide formation is reported from poorly reactive aromatic amines and non-strained lactones under mild operating conditions using an organic bicyclic guanidine catalyst. This protocol has high application potential as exemplified by the formal syntheses of drug-relevant molecules.
Àrees temàtiques: Química; Materials science (miscellaneous); Materials science (all); Materiais; Interdisciplinar; Green & sustainable science & technology; General materials science; General energy; General chemical engineering; Farmacia; Environmental chemistry; Engenharias iii; Engenharias ii; Energy (miscellaneous); Energy (all); Chemistry, multidisciplinary; Chemical engineering (miscellaneous); Chemical engineering (all); Biotecnología; Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
Adreça de correu electrònic de l'autor: carles.bo@urv.cat
Data d'alta del registre: 2025-02-19
Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
Enllaç font original: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.201700415
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Chemsuschem. 10 (9): 1969-1975
Referència de l'ítem segons les normes APA: Guo, Wusheng; Gomez, Jose Enrique; Martinez-Rodriguez, Luis; Bandeira, Nuno A G; Bo, Carles; Kleij, Arjan W (2017). Metal‐Free Synthesis of N‐Aryl Amides using Organocatalytic Ring‐Opening Aminolysis of Lactones. Chemsuschem, 10(9), 1969-1975. DOI: 10.1002/cssc.201700415
DOI de l'article: 10.1002/cssc.201700415
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2017
Tipus de publicació: Journal Publications
Repositori URV