Articles producció científica> Química Física i Inorgànica

Transition-metal-free stereoselective borylation of allenamides

  • Dades identificatives

    Identificador:  imarina:5132815
    Handle:  https://hdl.handle.net/20.500.11797/imarina5132815
    Autors:  Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J; Vicario, Jose L; Fernandez, Elena
    Resum:
    Complete stereocontrol on the transition‐metal‐free hydroboration of the distal double bond of allenamides could be achieved when allenamides contained acetyl substituents, which provided exclusively the Z‐isomer. The consecutive Pd‐catalyzed cross‐coupling reaction allowed the straightforward formation of trisubstituted enamides, with total control of the stereoselectivity.

  • Altres:

    Autor segons l'article: Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J; Vicario, Jose L; Fernandez, Elena
    Departament: Química Física i Inorgànica
    Autor/s de la URV: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena / MIRALLES PRAT, NURIA
    Paraules clau: Transition-metal free; Stereoselectivity; Density functional calculations; Borylation; Allenamines; stereoselectivity; density functional calculations; borylation; allenamines
    Resum: Complete stereocontrol on the transition‐metal‐free hydroboration of the distal double bond of allenamides could be achieved when allenamides contained acetyl substituents, which provided exclusively the Z‐isomer. The consecutive Pd‐catalyzed cross‐coupling reaction allowed the straightforward formation of trisubstituted enamides, with total control of the stereoselectivity.
    Àrees temàtiques: Química; Organic chemistry; Medicina i; Materiais; Interdisciplinar; General medicine; General chemistry; Farmacia; Engenharias iii; Engenharias ii; Ciências biológicas iii; Ciências biológicas ii; Ciências biológicas i; Ciências agrárias i; Chemistry, multidisciplinary; Chemistry (miscellaneous); Chemistry (all); Chemistry; Catalysis; Biotecnología; Biodiversidade; Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 15213765
    Adreça de correu electrònic de l'autor: j.carbo@urv.cat; mariaelena.fernandez@urv.cat
    Data d'alta del registre: 2025-02-18
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Enllaç font original: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201803004
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Chemistry-A European Journal. 24 (53): 14059-14063
    Referència de l'ítem segons les normes APA: Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J; Vicario, Jose L; Fernandez, Elena (2018). Transition-metal-free stereoselective borylation of allenamides. Chemistry-A European Journal, 24(53), 14059-14063. DOI: 10.1002/chem.201803004
    DOI de l'article: 10.1002/chem.201803004
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2018
    Tipus de publicació: Journal Publications

  • Paraules clau:

    Catalysis,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Organic Chemistry
    Transition-metal free
    Stereoselectivity
    Density functional calculations
    Borylation
    Allenamines
    stereoselectivity
    density functional calculations
    borylation
    allenamines
    Química
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física

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