Articles producció científica> Química Física i Inorgànica

Transition-metal-free stereoselective borylation of allenamides

  • Datos identificativos

    Identificador: imarina:5132815
    Handle: https://hdl.handle.net/20.500.11797/imarina5132815
    Autores:
    Garcia, LorenaSendra, JanaMiralles, NuriaReyes, EfraimCarbo, Jorge J.Vicario, Jose L.Fernandez, Elena
    Resumen:
    Complete stereocontrol on the transition‐metal‐free hydroboration of the distal double bond of allenamides could be achieved when allenamides contained acetyl substituents, which provided exclusively the Z‐isomer. The consecutive Pd‐catalyzed cross‐coupling reaction allowed the straightforward formation of trisubstituted enamides, with total control of the stereoselectivity.

  • Otros:

    Autor según el artículo: Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J.; Vicario, Jose L.; Fernandez, Elena;
    Departamento: Química Física i Inorgànica
    Autor/es de la URV: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena / MIRALLES PRAT, NURIA
    Palabras clave: Transition-metal free Stereoselectivity Density functional calculations Borylation Allenamines stereoselectivity density functional calculations borylation allenamines
    Resumen: Complete stereocontrol on the transition‐metal‐free hydroboration of the distal double bond of allenamides could be achieved when allenamides contained acetyl substituents, which provided exclusively the Z‐isomer. The consecutive Pd‐catalyzed cross‐coupling reaction allowed the straightforward formation of trisubstituted enamides, with total control of the stereoselectivity.
    Áreas temáticas: Química Organic chemistry Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biotecnología Biodiversidade Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 15213765
    Direcció de correo del autor: j.carbo@urv.cat mariaelena.fernandez@urv.cat
    Identificador del autor: 0000-0002-3945-6721 0000-0001-9025-1791
    Fecha de alta del registro: 2024-09-21
    Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Chemistry-A European Journal. 24 (53): 14059-14063
    Referencia de l'ítem segons les normes APA: Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J.; Vicario, Jose L.; Fernandez, Elena; (2018). Transition-metal-free stereoselective borylation of allenamides. Chemistry-A European Journal, 24(53), 14059-14063. DOI: 10.1002/chem.201803004
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2018
    Tipo de publicación: Journal Publications

  • Palabras clave:

    Catalysis,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Organic Chemistry
    Transition-metal free
    Stereoselectivity
    Density functional calculations
    Borylation
    Allenamines
    stereoselectivity
    density functional calculations
    borylation
    allenamines
    Química
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física

  • Documentos:

    DocumentPrincipal

  • Cerca a google

    Search to google scholar