Articles producció científica> Química Física i Inorgànica

Transition-metal-free stereoselective borylation of allenamides

  • Identification data

    Identifier: imarina:5132815
    Handle: https://hdl.handle.net/20.500.11797/imarina5132815
    Authors:
    Garcia, LorenaSendra, JanaMiralles, NuriaReyes, EfraimCarbo, Jorge J.Vicario, Jose L.Fernandez, Elena
    Abstract:
    Complete stereocontrol on the transition‐metal‐free hydroboration of the distal double bond of allenamides could be achieved when allenamides contained acetyl substituents, which provided exclusively the Z‐isomer. The consecutive Pd‐catalyzed cross‐coupling reaction allowed the straightforward formation of trisubstituted enamides, with total control of the stereoselectivity.

  • Others:

    Author, as appears in the article.: Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J.; Vicario, Jose L.; Fernandez, Elena;
    Department: Química Física i Inorgànica
    URV's Author/s: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena / MIRALLES PRAT, NURIA
    Keywords: Transition-metal free Stereoselectivity Density functional calculations Borylation Allenamines stereoselectivity density functional calculations borylation allenamines
    Abstract: Complete stereocontrol on the transition‐metal‐free hydroboration of the distal double bond of allenamides could be achieved when allenamides contained acetyl substituents, which provided exclusively the Z‐isomer. The consecutive Pd‐catalyzed cross‐coupling reaction allowed the straightforward formation of trisubstituted enamides, with total control of the stereoselectivity.
    Thematic Areas: Química Organic chemistry Medicina i Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iii Engenharias ii Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Catalysis Biotecnología Biodiversidade Astronomia / física
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 15213765
    Author's mail: j.carbo@urv.cat mariaelena.fernandez@urv.cat
    Author identifier: 0000-0002-3945-6721 0000-0001-9025-1791
    Record's date: 2024-09-21
    Papper version: info:eu-repo/semantics/acceptedVersion
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Papper original source: Chemistry-A European Journal. 24 (53): 14059-14063
    APA: Garcia, Lorena; Sendra, Jana; Miralles, Nuria; Reyes, Efraim; Carbo, Jorge J.; Vicario, Jose L.; Fernandez, Elena; (2018). Transition-metal-free stereoselective borylation of allenamides. Chemistry-A European Journal, 24(53), 14059-14063. DOI: 10.1002/chem.201803004
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2018
    Publication Type: Journal Publications

  • Keywords:

    Catalysis,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Organic Chemistry
    Transition-metal free
    Stereoselectivity
    Density functional calculations
    Borylation
    Allenamines
    stereoselectivity
    density functional calculations
    borylation
    allenamines
    Química
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iii
    Engenharias ii
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física

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