Articles producció científicaQuímica Física i Inorgànica

Transition-metal-free stereoselective borylation of allenamides

  • Identification data

    Identifier:  imarina:5132815
    Handle: https://hdl.handle.net/20.500.11797/imarina5132815
    Authors:  García, L; Sendra, J; Miralles, N; Reyes, E; Carbó, JJ; Vicario, JL; Fernández, E
    Abstract:
    Complete stereocontrol on the transition‐metal‐free hydroboration of the distal double bond of allenamides could be achieved when allenamides contained acetyl substituents, which provided exclusively the Z‐isomer. The consecutive Pd‐catalyzed cross‐coupling reaction allowed the straightforward formation of trisubstituted enamides, with total control of the stereoselectivity.

  • Others:

    Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/chem.201803004
    APA: García, L; Sendra, J; Miralles, N; Reyes, E; Carbó, JJ; Vicario, JL; Fernández, E (2018). Transition-metal-free stereoselective borylation of allenamides. Chemistry-A European Journal, 24(53), 14059-14063. DOI: 10.1002/chem.201803004
    Paper original source: Chemistry-A European Journal. 24 (53): 14059-14063
    Article's DOI: 10.1002/chem.201803004
    Journal publication year: 2018-09-20
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2026-05-09
    URV's Author/s: Carbó Martin, Jorge Juan / Fernández Gutiérrez, Maria Elena / MIRALLES PRAT, NURIA
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    ISSN: 15213765
    Author, as appears in the article.: García, L; Sendra, J; Miralles, N; Reyes, E; Carbó, JJ; Vicario, JL; Fernández, E
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Organic chemistry, General medicine, General chemistry, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Catalysis, Biotecnología, Biodiversidade
    Author's mail: j.carbo@urv.cat, j.carbo@urv.cat, mariaelena.fernandez@urv.cat, mariaelena.fernandez@urv.cat

  • Keywords:

    Transition-metal free
    Stereoselectivity
    Density functional calculations
    Borylation
    Allenamines
    Catalysis
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Organic Chemistry
    General medicine
    General chemistry
    Chemistry (all)
    Biotecnología
    Biodiversidade

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