Articles producció científicaQuímica Analítica i Química Orgànica

Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands

  • Dades identificatives

    Identificador:  imarina:5874630
    Handle: https://hdl.handle.net/20.500.11797/imarina5874630
    Autors:  Delgado-Rebollo, Manuela; Garcia-Morales, Cristina; Maya, Celia; Prieto, Auxiliadora; Echavarren, Antonio M; Perez, Pedro J
    Resum:
    The synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies. (C) 2019 Elsevier B.V. All rights reserved.

  • Altres:

    Enllaç font original: https://www.sciencedirect.com/science/article/abs/pii/S0022328X19302906?via%3Dihub
    Referència de l'ítem segons les normes APA: Delgado-Rebollo, Manuela; Garcia-Morales, Cristina; Maya, Celia; Prieto, Auxiliadora; Echavarren, Antonio M; Perez, Pedro J (2019). Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands. Journal Of Organometallic Chemistry, 898(UNSP 120856), 120856-. DOI: 10.1016/j.jorganchem.2019.07.007
    Referència a l'article segons font original: Journal Of Organometallic Chemistry. 898 (UNSP 120856): 120856-
    DOI de l'article: 10.1016/j.jorganchem.2019.07.007
    Any de publicació de la revista: 2019
    Entitat: Universitat Rovira i Virgili
    Versió de l'article dipositat: info:eu-repo/semantics/acceptedVersion
    Data d'alta del registre: 2025-02-19
    Autor/s de la URV: ECHAVARREN PABLOS, ANTONIO
    Departament: Química Analítica i Química Orgànica
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Tipus de publicació: Journal Publications
    ISSN: 0022328X
    Autor segons l'article: Delgado-Rebollo, Manuela; Garcia-Morales, Cristina; Maya, Celia; Prieto, Auxiliadora; Echavarren, Antonio M; Perez, Pedro J
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Àrees temàtiques: Química, Physical and theoretical chemistry, Organic chemistry, Materials chemistry, Materiais, Interdisciplinar, Inorganic chemistry, Farmacia, Engenharias ii, Ciências biológicas ii, Ciências agrárias i, Chemistry, organic, Chemistry, inorganic & nuclear, Biochemistry, Astronomia / física
    Adreça de correu electrònic de l'autor: antoniomaria.echavarren@urv.cat

  • Paraules clau:

    Structural-characterization
    Silver(i)
    Silver carbene
    Olefin metathesis
    Neutral and cationic complexes
    Gold carbene
    Fluorinated n-heterocyclic carbenes
    Copper carbene
    Catalysts
    Biochemistry
    Chemistry
    Inorganic & Nuclear
    Organic
    Inorganic Chemistry
    Materials Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias ii
    Ciências biológicas ii
    Ciências agrárias i
    Astronomia / física

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