Articles producció científicaQuímica Analítica i Química Orgànica

Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands

  • Datos identificativos

    Identificador:  imarina:5874630
    Handle: https://hdl.handle.net/20.500.11797/imarina5874630
    Autores:  Delgado-Rebollo, M; García-Morales, C; Maya, C; Prieto, A; Echavarren, AM; Pérez, PJ
    Resumen:
    The synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies. (C) 2019 Elsevier B.V. All rights reserved.

  • Otros:

    Enlace a la fuente original: https://www.sciencedirect.com/science/article/abs/pii/S0022328X19302906?via%3Dihub
    Referencia de l'ítem segons les normes APA: Delgado-Rebollo, M; García-Morales, C; Maya, C; Prieto, A; Echavarren, AM; Pérez, PJ (2019). Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands. Journal Of Organometallic Chemistry, 898(UNSP 120856), 120856-. DOI: 10.1016/j.jorganchem.2019.07.007
    Referencia al articulo segun fuente origial: Journal Of Organometallic Chemistry. 898 (UNSP 120856): 120856-
    DOI del artículo: 10.1016/j.jorganchem.2019.07.007
    Año de publicación de la revista: 2019-10-15
    Entidad: Universitat Rovira i Virgili
    Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
    Fecha de alta del registro: 2026-05-09
    Autor/es de la URV: ECHAVARREN PABLOS, ANTONIO
    Departamento: Química Analítica i Química Orgànica
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Tipo de publicación: Journal Publications
    ISSN: 0022328X
    Autor según el artículo: Delgado-Rebollo, M; García-Morales, C; Maya, C; Prieto, A; Echavarren, AM; Pérez, PJ
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    Áreas temáticas: Physical and theoretical chemistry, Organic chemistry, Materials chemistry, Inorganic chemistry, Engenharias ii, Ciências agrárias i, Chemistry, organic, Chemistry, inorganic & nuclear, Biochemistry, Astronomia / física
    Direcció de correo del autor: antoniomaria.echavarren@urv.cat, antoniomaria.echavarren@urv.cat

  • Palabras clave:

    Structural-characterization
    Silver(i)
    Silver carbene
    Olefin metathesis
    Neutral and cationic complexes
    Gold carbene
    Fluorinated n-heterocyclic carbenes
    Copper carbene
    Catalysts
    Biochemistry
    Chemistry
    Inorganic & Nuclear
    Organic
    Inorganic Chemistry
    Materials Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Engenharias ii
    Ciências agrárias i
    Astronomia / física

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