Autor según el artículo: Delgado-Rebollo, Manuela; Garcia-Morales, Cristina; Maya, Celia; Prieto, Auxiliadora; Echavarren, Antonio M.; Perez, Pedro J.;
Departamento: Química Analítica i Química Orgànica
Autor/es de la URV: ECHAVARREN PABLOS, ANTONIO
Palabras clave: Structural-characterization Silver(i) Silver carbene Olefin metathesis Neutral and cationic complexes Gold carbene Fluorinated n-heterocyclic carbenes Copper carbene Catalysts
Resumen: The synthesis of novel fluorinated symmetrical and unsymmetrical imidazolium salts as well as their corresponding coinage metal complexes is described. The silver derivatives were prepared using Ag2O as the metal source and the subsequent (NHC)AgX complexes were successfully employed in the preparation of the corresponding Cu(I) and Au(I) complexes through transmetallation reactions. Halide extrusion from (NHC)AuCl complexes in the presence of labile ligands also allowed the isolation of Au(I) cationic complexes [(NHC)Au(L)]X. The molecular structures of relevant examples of the neutral and ionic complexes have been unambiguously determined by X-ray studies. (C) 2019 Elsevier B.V. All rights reserved.
Áreas temáticas: Química Physical and theoretical chemistry Organic chemistry Materials chemistry Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias ii Ciências biológicas ii Ciências agrárias i Chemistry, organic Chemistry, inorganic & nuclear Biochemistry Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 0022328X
Direcció de correo del autor: antoniomaria.echavarren@urv.cat
Identificador del autor: 0000-0002-6418-7930
Fecha de alta del registro: 2022-07-23
Versión del articulo depositado: info:eu-repo/semantics/acceptedVersion
Enlace a la fuente original: https://www.sciencedirect.com/science/article/abs/pii/S0022328X19302906?via%3Dihub
Referencia al articulo segun fuente origial: Journal Of Organometallic Chemistry. 898 (UNSP 120856):
Referencia de l'ítem segons les normes APA: Delgado-Rebollo, Manuela; Garcia-Morales, Cristina; Maya, Celia; Prieto, Auxiliadora; Echavarren, Antonio M.; Perez, Pedro J.; (2019). Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands. Journal Of Organometallic Chemistry, 898(UNSP 120856), -. DOI: 10.1016/j.jorganchem.2019.07.007
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
DOI del artículo: 10.1016/j.jorganchem.2019.07.007
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2019
Tipo de publicación: Journal Publications
Repositori URV