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Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis

  • Dades identificatives

    Identificador: imarina:5874685
    Autors:
    Mato, MauroGarcia-Morales, CristinaEchavarren, Antonio M
    Resum:
    The gold(I)-catalyzed retro-Buchner (decarbenation, retrocyclopropanation) reaction of 7-substituted cycloheptatrienes has emerged as a safe and powerful alternative for the generation of gold(I) carbenes. These carbenes can cyclopropanate alkenes, take part in intramolecular reactions, or engage in higher cycloadditions with different partners, giving rise to a wide range of relevant structures. This review covers the developments made on the generation of gold(I) carbenes via decarbenation reactions, and the applications of these reactions in organic synthesis.
  • Altres:

    Autor segons l'article: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M
    Departament: Química Analítica i Química Orgànica
    Autor/s de la URV: ECHAVARREN PABLOS, ANTONIO / Mato Gómez, Mauro / Muro Morales, José Ignacio
    Paraules clau: Total synthesis Selective inhibitors Retro-buchner reaction Radical decarboxylation Nmr-spectroscopy Molecular complexity Lactobacillic acid Intermolecular 2+2 cycloaddition Gold catalysis Enantioselective total-synthesis Derivatives Cyclopropanation Cycloadditions Catalyzed oxidative cyclization A-c
    Resum: The gold(I)-catalyzed retro-Buchner (decarbenation, retrocyclopropanation) reaction of 7-substituted cycloheptatrienes has emerged as a safe and powerful alternative for the generation of gold(I) carbenes. These carbenes can cyclopropanate alkenes, take part in intramolecular reactions, or engage in higher cycloadditions with different partners, giving rise to a wide range of relevant structures. This review covers the developments made on the generation of gold(I) carbenes via decarbenation reactions, and the applications of these reactions in organic synthesis.
    Àrees temàtiques: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 18673880
    Adreça de correu electrònic de l'autor: antoniomaria.echavarren@urv.cat joseignacio.muro@urv.cat
    Identificador de l'autor: 0000-0002-6418-7930 0000-0003-0735-6117
    Data d'alta del registre: 2024-10-12
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201801201
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Chemcatchem. 11 (1): 53-72
    Referència de l'ítem segons les normes APA: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M (2019). Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis. Chemcatchem, 11(1), 53-72. DOI: 10.1002/cctc.201801201
    DOI de l'article: 10.1002/cctc.201801201
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2019
    Tipus de publicació: Journal Publications
  • Paraules clau:

    Catalysis,Chemistry, Physical,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
    Total synthesis
    Selective inhibitors
    Retro-buchner reaction
    Radical decarboxylation
    Nmr-spectroscopy
    Molecular complexity
    Lactobacillic acid
    Intermolecular 2+2 cycloaddition
    Gold catalysis
    Enantioselective total-synthesis
    Derivatives
    Cyclopropanation
    Cycloadditions
    Catalyzed oxidative cyclization
    A-c
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, physical
    Catalysis
    Biotecnología
    Astronomia / física
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