Autor segons l'article: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M
Departament: Química Analítica i Química Orgànica
Autor/s de la URV: ECHAVARREN PABLOS, ANTONIO / Mato Gómez, Mauro / Muro Morales, José Ignacio
Paraules clau: Total synthesis Selective inhibitors Retro-buchner reaction Radical decarboxylation Nmr-spectroscopy Molecular complexity Lactobacillic acid Intermolecular 2+2 cycloaddition Gold catalysis Enantioselective total-synthesis Derivatives Cyclopropanation Cycloadditions Catalyzed oxidative cyclization A-c
Resum: The gold(I)-catalyzed retro-Buchner (decarbenation, retrocyclopropanation) reaction of 7-substituted cycloheptatrienes has emerged as a safe and powerful alternative for the generation of gold(I) carbenes. These carbenes can cyclopropanate alkenes, take part in intramolecular reactions, or engage in higher cycloadditions with different partners, giving rise to a wide range of relevant structures. This review covers the developments made on the generation of gold(I) carbenes via decarbenation reactions, and the applications of these reactions in organic synthesis.
Àrees temàtiques: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 18673880
Adreça de correu electrònic de l'autor: antoniomaria.echavarren@urv.cat joseignacio.muro@urv.cat
Identificador de l'autor: 0000-0002-6418-7930 0000-0003-0735-6117
Data d'alta del registre: 2024-10-12
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Chemcatchem. 11 (1): 53-72
Referència de l'ítem segons les normes APA: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M (2019). Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis. Chemcatchem, 11(1), 53-72. DOI: 10.1002/cctc.201801201
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2019
Tipus de publicació: Journal Publications
Repositori URV