Articles producció científicaQuímica Analítica i Química Orgànica

Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis

  • Dades identificatives

    Identificador:  imarina:5874685
    Handle: https://hdl.handle.net/20.500.11797/imarina5874685
    Autors:  Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M
    Resum:
    The gold(I)-catalyzed retro-Buchner (decarbenation, retrocyclopropanation) reaction of 7-substituted cycloheptatrienes has emerged as a safe and powerful alternative for the generation of gold(I) carbenes. These carbenes can cyclopropanate alkenes, take part in intramolecular reactions, or engage in higher cycloadditions with different partners, giving rise to a wide range of relevant structures. This review covers the developments made on the generation of gold(I) carbenes via decarbenation reactions, and the applications of these reactions in organic synthesis.

  • Altres:

    Enllaç font original: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201801201
    Referència de l'ítem segons les normes APA: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M (2019). Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis. Chemcatchem, 11(1), 53-72. DOI: 10.1002/cctc.201801201
    Referència a l'article segons font original: Chemcatchem. 11 (1): 53-72
    DOI de l'article: 10.1002/cctc.201801201
    Any de publicació de la revista: 2019
    Entitat: Universitat Rovira i Virgili
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Data d'alta del registre: 2024-10-12
    Autor/s de la URV: ECHAVARREN PABLOS, ANTONIO / Mato Gómez, Mauro / Muro Morales, José Ignacio
    Departament: Química Analítica i Química Orgànica
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Tipus de publicació: Journal Publications
    ISSN: 18673880
    Autor segons l'article: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Àrees temàtiques: Química, Physical and theoretical chemistry, Organic chemistry, Medicina i, Materiais, Interdisciplinar, Inorganic chemistry, Farmacia, Engenharias iv, Engenharias iii, Engenharias ii, Engenharias i, Ciências biológicas ii, Ciências ambientais, Ciências agrárias i, Ciência de alimentos, Chemistry, physical, Catalysis, Biotecnología, Astronomia / física
    Adreça de correu electrònic de l'autor: antoniomaria.echavarren@urv.cat, joseignacio.muro@urv.cat

  • Paraules clau:

    Total synthesis
    Selective inhibitors
    Retro-buchner reaction
    Radical decarboxylation
    Nmr-spectroscopy
    Molecular complexity
    Lactobacillic acid
    Intermolecular 2+2 cycloaddition
    Gold catalysis
    Enantioselective total-synthesis
    Derivatives
    Cyclopropanation
    Cycloadditions
    Catalyzed oxidative cyclization
    A-c
    Catalysis
    Chemistry
    Physical
    Inorganic Chemistry
    Organic Chemistry
    Physical and Theoretical Chemistry
    Química
    Medicina i
    Materiais
    Interdisciplinar
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Biotecnología
    Astronomia / física

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