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Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis

  • Datos identificativos

    Identificador: imarina:5874685
    Autores:
    Mato, MauroGarcia-Morales, CristinaEchavarren, Antonio M
    Resumen:
    The gold(I)-catalyzed retro-Buchner (decarbenation, retrocyclopropanation) reaction of 7-substituted cycloheptatrienes has emerged as a safe and powerful alternative for the generation of gold(I) carbenes. These carbenes can cyclopropanate alkenes, take part in intramolecular reactions, or engage in higher cycloadditions with different partners, giving rise to a wide range of relevant structures. This review covers the developments made on the generation of gold(I) carbenes via decarbenation reactions, and the applications of these reactions in organic synthesis.
  • Otros:

    Autor según el artículo: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M
    Departamento: Química Analítica i Química Orgànica
    Autor/es de la URV: ECHAVARREN PABLOS, ANTONIO / Mato Gómez, Mauro / Muro Morales, José Ignacio
    Palabras clave: Total synthesis Selective inhibitors Retro-buchner reaction Radical decarboxylation Nmr-spectroscopy Molecular complexity Lactobacillic acid Intermolecular 2+2 cycloaddition Gold catalysis Enantioselective total-synthesis Derivatives Cyclopropanation Cycloadditions Catalyzed oxidative cyclization A-c
    Resumen: The gold(I)-catalyzed retro-Buchner (decarbenation, retrocyclopropanation) reaction of 7-substituted cycloheptatrienes has emerged as a safe and powerful alternative for the generation of gold(I) carbenes. These carbenes can cyclopropanate alkenes, take part in intramolecular reactions, or engage in higher cycloadditions with different partners, giving rise to a wide range of relevant structures. This review covers the developments made on the generation of gold(I) carbenes via decarbenation reactions, and the applications of these reactions in organic synthesis.
    Áreas temáticas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
    Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
    ISSN: 18673880
    Direcció de correo del autor: antoniomaria.echavarren@urv.cat joseignacio.muro@urv.cat
    Identificador del autor: 0000-0002-6418-7930 0000-0003-0735-6117
    Fecha de alta del registro: 2024-10-12
    Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
    Enlace a la fuente original: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201801201
    URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referencia al articulo segun fuente origial: Chemcatchem. 11 (1): 53-72
    Referencia de l'ítem segons les normes APA: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M (2019). Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis. Chemcatchem, 11(1), 53-72. DOI: 10.1002/cctc.201801201
    DOI del artículo: 10.1002/cctc.201801201
    Entidad: Universitat Rovira i Virgili
    Año de publicación de la revista: 2019
    Tipo de publicación: Journal Publications
  • Palabras clave:

    Catalysis,Chemistry, Physical,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
    Total synthesis
    Selective inhibitors
    Retro-buchner reaction
    Radical decarboxylation
    Nmr-spectroscopy
    Molecular complexity
    Lactobacillic acid
    Intermolecular 2+2 cycloaddition
    Gold catalysis
    Enantioselective total-synthesis
    Derivatives
    Cyclopropanation
    Cycloadditions
    Catalyzed oxidative cyclization
    A-c
    Química
    Physical and theoretical chemistry
    Organic chemistry
    Medicina i
    Materiais
    Interdisciplinar
    Inorganic chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Ciências biológicas ii
    Ciências ambientais
    Ciências agrárias i
    Ciência de alimentos
    Chemistry, physical
    Catalysis
    Biotecnología
    Astronomia / física
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