Author, as appears in the article.: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M
Department: Química Analítica i Química Orgànica
URV's Author/s: ECHAVARREN PABLOS, ANTONIO / Mato Gómez, Mauro / Muro Morales, José Ignacio
Keywords: Total synthesis Selective inhibitors Retro-buchner reaction Radical decarboxylation Nmr-spectroscopy Molecular complexity Lactobacillic acid Intermolecular 2+2 cycloaddition Gold catalysis Enantioselective total-synthesis Derivatives Cyclopropanation Cycloadditions Catalyzed oxidative cyclization A-c
Abstract: The gold(I)-catalyzed retro-Buchner (decarbenation, retrocyclopropanation) reaction of 7-substituted cycloheptatrienes has emerged as a safe and powerful alternative for the generation of gold(I) carbenes. These carbenes can cyclopropanate alkenes, take part in intramolecular reactions, or engage in higher cycloadditions with different partners, giving rise to a wide range of relevant structures. This review covers the developments made on the generation of gold(I) carbenes via decarbenation reactions, and the applications of these reactions in organic synthesis.
Thematic Areas: Química Physical and theoretical chemistry Organic chemistry Medicina i Materiais Interdisciplinar Inorganic chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Ciências biológicas ii Ciências ambientais Ciências agrárias i Ciência de alimentos Chemistry, physical Catalysis Biotecnología Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 18673880
Author's mail: antoniomaria.echavarren@urv.cat joseignacio.muro@urv.cat
Author identifier: 0000-0002-6418-7930 0000-0003-0735-6117
Record's date: 2024-10-12
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201801201
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Chemcatchem. 11 (1): 53-72
APA: Mato, Mauro; Garcia-Morales, Cristina; Echavarren, Antonio M (2019). Generation of Gold(I) Carbenes by Retro-Buchner Reaction: From Cyclopropanes to Natural Products Synthesis. Chemcatchem, 11(1), 53-72. DOI: 10.1002/cctc.201801201
Article's DOI: 10.1002/cctc.201801201
Entity: Universitat Rovira i Virgili
Journal publication year: 2019
Publication Type: Journal Publications
Repositori URV