Autor segons l'article: Salvadó O; Fernández E
Departament: Química Física i Inorgànica
Autor/s de la URV: Fernández Gutiérrez, Maria Elena / Fernández López, Elena / Salvadó Ruiz, Oriol
Paraules clau: Terminal alkynes Synthetic approaches Synthetic applications Ketones Esters Diboration Construction Borylation Alkylation Aldehydes 1,2,3-tri(boryl)alkanes 1,1,2-tri(boryl)alkanes 1,1,2-tri(boryl) alkenes 1,1,1-tri(boryl)alkanes synthetic applications 1,2,3-tri(boryl)alkanes 1,1,2-tri(boryl)alkenes 1,1,2-tri(boryl)alkanes 1,1,1-tri(boryl)alkanes
Resum: © 2020 by the authors. The interest of organoboron chemistry in organic synthesis is growing, together with the development of new and versatile polyborated reagents. Here, the preparation of 1,1,1-tri(boryl)alkanes, 1,2,3-tri(boryl)alkanes, 1,1,2-tri(boryl)alkanes, as well as 1,1,2-tri(boryl)alkenes as suitable and accessible polyborated systems is demonstrated as being easily applied in the construction of new carbon-carbon and carbon-heteroatom bonds. Synthetic procedures and limitations have been collected to demonstrate the powerful strategies to construct selective molecules, taking advantages of the easy transformation of carbon-boron bond in multiple functionalities, under the total control of chemo- and stereoselectivity.
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Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 14203049
Adreça de correu electrònic de l'autor: oriol.salvado@urv.cat mariaelena.fernandez@urv.cat
Identificador de l'autor: 0000-0001-9025-1791
Data d'alta del registre: 2024-10-26
Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
Enllaç font original: https://www.mdpi.com/1420-3049/25/7/1758
URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
Referència a l'article segons font original: Molecules. 25 (7):
Referència de l'ítem segons les normes APA: Salvadó O; Fernández E (2020). Tri(boryl)alkanes and tri(boryl)alkenes: The versatile reagents. Molecules, 25(7), -. DOI: 10.3390/molecules25071758
DOI de l'article: 10.3390/molecules25071758
Entitat: Universitat Rovira i Virgili
Any de publicació de la revista: 2020
Tipus de publicació: Journal Publications