Tri(boryl)alkanes and tri(boryl)alkenes: The versatile reagents

Autor segons l'article: Salvado, Oriol; Fernandez, Elena

Departament: Química Física i Inorgànica

Autor/s de la URV: Fernández Gutiérrez, Maria Elena / Fernández López, Elena / Salvadó Ruiz, Oriol

Paraules clau: Terminal alkynes; Synthetic approaches; Synthetic applications; Stereoisomerism; Models, chemical; Ketones; Esters; Diboration; Construction; Chemistry techniques, synthetic; Borylation; Alkylation; Alkenes; Aldehydes; 1,2,3-tri(boryl)alkanes; 1,1,2-tri(boryl)alkenes; 1,1,2-tri(boryl)alkanes; 1,1,2-tri(boryl) alkenes; 1,1,1-tri(boryl)alkanes; synthetic applications; 1,2,3-tri(boryl)alkanes; 1,1,2-tri(boryl)alkenes; 1,1,2-tri(boryl)alkanes; 1,1,1-tri(boryl)alkanes

Resum: © 2020 by the authors. The interest of organoboron chemistry in organic synthesis is growing, together with the development of new and versatile polyborated reagents. Here, the preparation of 1,1,1-tri(boryl)alkanes, 1,2,3-tri(boryl)alkanes, 1,1,2-tri(boryl)alkanes, as well as 1,1,2-tri(boryl)alkenes as suitable and accessible polyborated systems is demonstrated as being easily applied in the construction of new carbon-carbon and carbon-heteroatom bonds. Synthetic procedures and limitations have been collected to demonstrate the powerful strategies to construct selective molecules, taking advantages of the easy transformation of carbon-boron bond in multiple functionalities, under the total control of chemo- and stereoselectivity.

Àrees temàtiques: Zootecnia / recursos pesqueiros; Saúde coletiva; Química; Psicología; Planejamento urbano e regional / demografia; Physical and theoretical chemistry; Pharmaceutical science; Organic chemistry; Odontología; Nutrição; Molecular medicine; Medicine (miscellaneous); Medicina veterinaria; Medicina iii; Medicina ii; Medicina i; Materiais; Matemática / probabilidade e estatística; Interdisciplinar; Geografía; General medicine; Farmacia; Ensino; Engenharias iv; Engenharias iii; Engenharias ii; Engenharias i; Educação física; Economia; Drug discovery; Ciências biológicas iii; Ciências biológicas ii; Ciências biológicas i; Ciências ambientais; Ciências agrárias i; Ciência de alimentos; Ciência da computação; Chemistry, organic; Chemistry, multidisciplinary; Chemistry (miscellaneous); Biotecnología; Biodiversidade; Biochemistry & molecular biology; Astronomia / física; Analytical chemistry

Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/

ISSN: 14203049

Adreça de correu electrònic de l'autor: oriol.salvado@alumni.urv.cat; mariaelena.fernandez@urv.cat

Data d'alta del registre: 2025-02-18

Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion

Enllaç font original: https://www.mdpi.com/1420-3049/25/7/1758

URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/

Referència a l'article segons font original: Molecules. 25 (7): 1758-

Referència de l'ítem segons les normes APA: Salvado, Oriol; Fernandez, Elena (2020). Tri(boryl)alkanes and tri(boryl)alkenes: The versatile reagents. Molecules, 25(7), 1758-. DOI: 10.3390/molecules25071758

DOI de l'article: 10.3390/molecules25071758

Entitat: Universitat Rovira i Virgili

Any de publicació de la revista: 2020

Tipus de publicació: Journal Publications