Author, as appears in the article.: Salvadó O; Fernández E
Department: Química Física i Inorgànica
URV's Author/s: Fernández Gutiérrez, Maria Elena / Fernández López, Elena / Salvadó Ruiz, Oriol
Keywords: Terminal alkynes Synthetic approaches Synthetic applications Ketones Esters Diboration Construction Borylation Alkylation Aldehydes 1,2,3-tri(boryl)alkanes 1,1,2-tri(boryl)alkanes 1,1,2-tri(boryl) alkenes 1,1,1-tri(boryl)alkanes synthetic applications 1,2,3-tri(boryl)alkanes 1,1,2-tri(boryl)alkenes 1,1,2-tri(boryl)alkanes 1,1,1-tri(boryl)alkanes
Abstract: © 2020 by the authors. The interest of organoboron chemistry in organic synthesis is growing, together with the development of new and versatile polyborated reagents. Here, the preparation of 1,1,1-tri(boryl)alkanes, 1,2,3-tri(boryl)alkanes, 1,1,2-tri(boryl)alkanes, as well as 1,1,2-tri(boryl)alkenes as suitable and accessible polyborated systems is demonstrated as being easily applied in the construction of new carbon-carbon and carbon-heteroatom bonds. Synthetic procedures and limitations have been collected to demonstrate the powerful strategies to construct selective molecules, taking advantages of the easy transformation of carbon-boron bond in multiple functionalities, under the total control of chemo- and stereoselectivity.
Thematic Areas: Zootecnia / recursos pesqueiros Saúde coletiva Química Psicología Planejamento urbano e regional / demografia Physical and theoretical chemistry Pharmaceutical science Organic chemistry Odontología Nutrição Molecular medicine Medicine (miscellaneous) Medicina veterinaria Medicina iii Medicina ii Medicina i Materiais Matemática / probabilidade e estatística Interdisciplinar Geografía General medicine Farmacia Ensino Engenharias iv Engenharias iii Engenharias ii Engenharias i Educação física Economia Drug discovery Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Ciência de alimentos Ciência da computação Chemistry, organic Chemistry, multidisciplinary Chemistry (miscellaneous) Biotecnología Biodiversidade Biochemistry & molecular biology Astronomia / física Analytical chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 14203049
Author's mail: oriol.salvado@urv.cat mariaelena.fernandez@urv.cat
Author identifier: 0000-0001-9025-1791
Record's date: 2024-10-26
Papper version: info:eu-repo/semantics/publishedVersion
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Papper original source: Molecules. 25 (7):
APA: Salvadó O; Fernández E (2020). Tri(boryl)alkanes and tri(boryl)alkenes: The versatile reagents. Molecules, 25(7), -. DOI: 10.3390/molecules25071758
Entity: Universitat Rovira i Virgili
Journal publication year: 2020
Publication Type: Journal Publications
Repositori URV