Determination of mycotoxins in plant-based beverages using QuEChERS and liquid chromatography–tandem mass spectrometry

Identificador:  imarina:6389033

Handle: https://hdl.handle.net/20.500.11797/imarina6389033

Autors:  Miró-Abella, E; Herrero, P; Canela, N; Arola, L; Borrull, F; Ras, R; Fontanals, N

Resum:
© 2017 Elsevier Ltd A method was developed for the simultaneous determination of 11 mycotoxins in plant-based beverage matrices, using a QuEChERS extraction followed by ultra-high performance liquid chromatography coupled to tandem mass spectrometry detection (UHPLC–(ESI)MS/MS). This multi-mycotoxin method was applied to analyse plant-based beverages such as soy, oat and rice. QuEChERS extraction was applied obtaining suitable extraction recoveries between 80 and 91%, and good repeatability and reproducibility values. Method Quantification Limits were between 0.05 μg L−1 (for aflatoxin G1 and aflatoxin B1) and 15 μg L−1 (for deoxynivalenol and fumonisin B2). This is the first time that plant-based beverages have been analysed, and certain mycotoxins, such as deoxynivalenol, aflatoxin B1, aflatoxin B2, aflatoxin G1, aflatoxin G2, ochratoxin A, T-2 toxin and zearalenone, were found in the analysed samples, and some of them quantified between 0.1 μg L−1 and 19 μg L−1.