Articles producció científica> Química Física i Inorgànica

Reactivity differences of Sc3N@C-2n (2n=68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D-5h-C-80

  • Dades identificatives

    Identificador: imarina:9297420
    Handle: https://hdl.handle.net/20.500.11797/imarina9297420
    Autors:
    Ceron, Maira RIzquierdo, MartaAlegret, NuriaValdez, Juan ARodriguez-Fortea, AntonioOlmstead, Marilyn MBalch, Alan LPoblet, Josep MEchegoyen, Luis
    Resum:
    Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@I-h-C-80 and Sc3N@D-3h-C-78 and a mixture of Sc3N@D-5h-C-80 and Sc3N@D-3-C-68. Taking advantage of their chemical reactivity differences, Sc3N@D-5h-C-80 was isolated from Sc3N@D-3-C-68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D-5h-C-80.

  • Altres:

    Autor segons l'article: Ceron, Maira R; Izquierdo, Marta; Alegret, Nuria; Valdez, Juan A; Rodriguez-Fortea, Antonio; Olmstead, Marilyn M; Balch, Alan L; Poblet, Josep M; Echegoyen, Luis
    Departament: Química Física i Inorgànica
    Autor/s de la URV: Poblet Rius, Josep Maria / Rodríguez Fortea, Antonio
    Paraules clau: Sc Purification M3n-at-c-80 m Isomers Isolated pentagon rule Fullerenes Endohedral metallofullerenes D-5h Cycloaddition Cluster
    Resum: Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@I-h-C-80 and Sc3N@D-3h-C-78 and a mixture of Sc3N@D-5h-C-80 and Sc3N@D-3-C-68. Taking advantage of their chemical reactivity differences, Sc3N@D-5h-C-80 was isolated from Sc3N@D-3-C-68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D-5h-C-80.
    Àrees temàtiques: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
    Accès a la llicència d'ús: https://creativecommons.org/licenses/by/3.0/es/
    Adreça de correu electrònic de l'autor: josepmaria.poblet@urv.cat antonio.rodriguezf@urv.cat
    Identificador de l'autor: 0000-0002-4533-0623 0000-0001-5884-5629
    Data d'alta del registre: 2024-10-12
    Versió de l'article dipositat: info:eu-repo/semantics/publishedVersion
    Enllaç font original: https://pubs.rsc.org/en/content/articlelanding/2016/cc/c5cc07416a
    URL Document de llicència: https://repositori.urv.cat/ca/proteccio-de-dades/
    Referència a l'article segons font original: Chemical Communications. 52 (1): 64-67
    Referència de l'ítem segons les normes APA: Ceron, Maira R; Izquierdo, Marta; Alegret, Nuria; Valdez, Juan A; Rodriguez-Fortea, Antonio; Olmstead, Marilyn M; Balch, Alan L; Poblet, Josep M; Eche (2016). Reactivity differences of Sc3N@C-2n (2n=68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D-5h-C-80. Chemical Communications, 52(1), 64-67. DOI: 10.1039/C5CC07416A
    DOI de l'article: 10.1039/C5CC07416A
    Entitat: Universitat Rovira i Virgili
    Any de publicació de la revista: 2016
    Tipus de publicació: Journal Publications

  • Paraules clau:

    Catalysis,Ceramics and Composites,Chemistry,Chemistry (Miscellaneous),Chemistry, Multidisciplinary,Electronic, Optical and Magnetic Materials,Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films
    Sc
    Purification
    M3n-at-c-80 m
    Isomers
    Isolated pentagon rule
    Fullerenes
    Endohedral metallofullerenes
    D-5h
    Cycloaddition
    Cluster
    Surfaces, coatings and films
    Química
    Metals and alloys
    Medicina ii
    Medicina i
    Materials chemistry
    Materiais
    Interdisciplinar
    General medicine
    General chemistry
    Farmacia
    Engenharias iv
    Engenharias iii
    Engenharias ii
    Engenharias i
    Electronic, optical and magnetic materials
    Ciências biológicas iii
    Ciências biológicas ii
    Ciências biológicas i
    Ciências ambientais
    Ciências agrárias i
    Chemistry, multidisciplinary
    Chemistry (miscellaneous)
    Chemistry (all)
    Chemistry
    Ceramics and composites
    Catalysis
    Biotecnología
    Biodiversidade
    Astronomia / física

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