Articles producció científicaQuímica Física i Inorgànica

Reactivity differences of Sc3N@C-2n (2n=68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D-5h-C-80

  • Identification data

    Identifier:  imarina:9297420
    Handle: https://hdl.handle.net/20.500.11797/imarina9297420
    Authors:  Cerón, MR; Izquierdo, M; Alegret, N; Valdez, JA; Rodriguez-Fortea, A; Olmstead, MM; Balch, AL; Poblet, JM; Echegoyen, L
    Abstract:
    Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@I-h-C-80 and Sc3N@D-3h-C-78 and a mixture of Sc3N@D-5h-C-80 and Sc3N@D-3-C-68. Taking advantage of their chemical reactivity differences, Sc3N@D-5h-C-80 was isolated from Sc3N@D-3-C-68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D-5h-C-80.

  • Others:

    Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2016/cc/c5cc07416a
    APA: Cerón, MR; Izquierdo, M; Alegret, N; Valdez, JA; Rodriguez-Fortea, A; Olmstead, MM; Balch, AL; Poblet, JM; Echegoyen, L (2016). Reactivity differences of Sc3N@C-2n (2n=68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D-5h-C-80. Chemical Communications, 52(1), 64-67. DOI: 10.1039/C5CC07416A
    Paper original source: Chemical Communications. 52 (1): 64-67
    Article's DOI: 10.1039/C5CC07416A
    Journal publication year: 2016-01-01
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2026-05-09
    URV's Author/s: Poblet Rius, Josep Maria / Rodríguez Fortea, Antonio
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Journal Publications
    Author, as appears in the article.: Cerón, MR; Izquierdo, M; Alegret, N; Valdez, JA; Rodriguez-Fortea, A; Olmstead, MM; Balch, AL; Poblet, JM; Echegoyen, L
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Thematic Areas: Surfaces, coatings and films, Metals and alloys, Materials chemistry, General medicine, General chemistry, Electronic, optical and magnetic materials, Chemistry, multidisciplinary, Chemistry (miscellaneous), Chemistry (all), Chemistry, Ceramics and composites, Catalysis, Biotecnología, Astronomia / física
    Author's mail: josepmaria.poblet@urv.cat, josepmaria.poblet@urv.cat, antonio.rodriguezf@urv.cat, antonio.rodriguezf@urv.cat

  • Keywords:

    Sc
    Purification
    M3n-at-c-80 m
    Isomers
    Isolated pentagon rule
    Fullerenes
    Endohedral metallofullerenes
    D-5h
    Cycloaddition
    Cluster
    Catalysis
    Ceramics and Composites
    Chemistry
    Chemistry (Miscellaneous)
    Multidisciplinary
    Electronic
    Optical and Magnetic Materials
    Materials Chemistry
    Metals and Alloys
    Surfaces
    Coatings and Films
    General medicine
    General chemistry
    Chemistry (all)
    Biotecnología
    Astronomia / física

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