Author, as appears in the article.: Ceron, Maira R.; Izquierdo, Marta; Alegret, Nuria; Valdez, Juan A.; Rodriguez-Fortea, Antonio; Olmstead, Marilyn M.; Balch, Alan L.; Poblet, Josep M.; Echegoyen, Luis;
Department: Química Física i Inorgànica
URV's Author/s: Poblet Rius, Josep Maria / Rodríguez Fortea, Antonio
Keywords: Sc Purification M3n-at-c-80 m Isomers Isolated pentagon rule Fullerenes Endohedral metallofullerenes D-5h Cycloaddition Cluster
Abstract: Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@I-h-C-80 and Sc3N@D-3h-C-78 and a mixture of Sc3N@D-5h-C-80 and Sc3N@D-3-C-68. Taking advantage of their chemical reactivity differences, Sc3N@D-5h-C-80 was isolated from Sc3N@D-3-C-68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D-5h-C-80.
Thematic Areas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
licence for use: https://creativecommons.org/licenses/by/3.0/es/
Author's mail: antonio.rodriguezf@urv.cat josepmaria.poblet@urv.cat
Author identifier: 0000-0001-5884-5629 0000-0002-4533-0623
Record's date: 2023-05-20
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: https://pubs.rsc.org/en/content/articlelanding/2016/cc/c5cc07416a
Papper original source: Chemical Communications. 52 (1): 64-67
APA: Ceron, Maira R.; Izquierdo, Marta; Alegret, Nuria; Valdez, Juan A.; Rodriguez-Fortea, Antonio; Olmstead, Marilyn M.; Balch, Alan L.; Poblet, Josep M.; (2016). Reactivity differences of Sc3N@C-2n (2n=68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D-5h-C-80. Chemical Communications, 52(1), 64-67. DOI: 10.1039/C5CC07416A
Licence document URL: http://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1039/C5CC07416A
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
Publication Type: Journal Publications
Repositori URV