Autor según el artículo: Ceron, Maira R; Izquierdo, Marta; Alegret, Nuria; Valdez, Juan A; Rodriguez-Fortea, Antonio; Olmstead, Marilyn M; Balch, Alan L; Poblet, Josep M; Echegoyen, Luis
Departamento: Química Física i Inorgànica
Autor/es de la URV: Poblet Rius, Josep Maria / Rodríguez Fortea, Antonio
Palabras clave: Sc Purification M3n-at-c-80 m Isomers Isolated pentagon rule Fullerenes Endohedral metallofullerenes D-5h Cycloaddition Cluster
Resumen: Using a purification method introduced earlier based on redox properties it was possible to isolate Sc3N@I-h-C-80 and Sc3N@D-3h-C-78 and a mixture of Sc3N@D-5h-C-80 and Sc3N@D-3-C-68. Taking advantage of their chemical reactivity differences, Sc3N@D-5h-C-80 was isolated from Sc3N@D-3-C-68 followed by further functionalization, giving rise to five new methano-derivatives of Sc3N@D-5h-C-80.
Áreas temáticas: Surfaces, coatings and films Química Metals and alloys Medicina ii Medicina i Materials chemistry Materiais Interdisciplinar General medicine General chemistry Farmacia Engenharias iv Engenharias iii Engenharias ii Engenharias i Electronic, optical and magnetic materials Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências ambientais Ciências agrárias i Chemistry, multidisciplinary Chemistry (miscellaneous) Chemistry (all) Chemistry Ceramics and composites Catalysis Biotecnología Biodiversidade Astronomia / física
Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/
Direcció de correo del autor: josepmaria.poblet@urv.cat antonio.rodriguezf@urv.cat
Identificador del autor: 0000-0002-4533-0623 0000-0001-5884-5629
Fecha de alta del registro: 2024-10-12
Versión del articulo depositado: info:eu-repo/semantics/publishedVersion
Enlace a la fuente original: https://pubs.rsc.org/en/content/articlelanding/2016/cc/c5cc07416a
URL Documento de licencia: https://repositori.urv.cat/ca/proteccio-de-dades/
Referencia al articulo segun fuente origial: Chemical Communications. 52 (1): 64-67
Referencia de l'ítem segons les normes APA: Ceron, Maira R; Izquierdo, Marta; Alegret, Nuria; Valdez, Juan A; Rodriguez-Fortea, Antonio; Olmstead, Marilyn M; Balch, Alan L; Poblet, Josep M; Eche (2016). Reactivity differences of Sc3N@C-2n (2n=68 and 80). Synthesis of the first methanofullerene derivatives of Sc3N@D-5h-C-80. Chemical Communications, 52(1), 64-67. DOI: 10.1039/C5CC07416A
DOI del artículo: 10.1039/C5CC07416A
Entidad: Universitat Rovira i Virgili
Año de publicación de la revista: 2016
Tipo de publicación: Journal Publications