Articles producció científica> Química Física i Inorgànica

Opportune gem-Silylborylation of Carbonyl Compounds: A Modular and Stereocontrolled Entry to Tetrasubstituted Olefins

  • Identification data

    Identifier: PC:2698
    Authors:
    Fernández, E.La Cascia, E.Cuenca, A.B.
    Abstract:
    author can archive pre-print (ie pre-refereeing). Post-print 12 meses de embargo Títol del pre-print: Opportune gem-silylborylation of carbonyl compounds: to generate in situ selective tetrasubstituted olefins DOI: 10.1002/chem.201604782 URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.201604782/abstract Filiació URV: SI
  • Others:

    Author, as appears in the article.: Fernández, E. ; La Cascia, E.; Cuenca, A.B.
    Department: Química Física i Inorgànica
    URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; La Cascia, E.; Cuenca, A.B.
    Keywords: gem-silyborylation
    Abstract: The stereocontrol on the synthesis of tetrasubstituted alkenes can be predicted by the use of gem-silaborated structures that perform selective silicon based or boron based cross-coupling reactions. Iododesilylation becomes a strategic issue to accomplish the target C-Si cross coupling. The easy access to gem-silaborated olefins, from ketones and HC(Bpin)2(SiMe3), is based on the strategic B-O olefination outcome.
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Química Química Chemistry
    ISSN: 0947-6539
    Author identifier: 0000-0001-9025-1791; n/a; 0000-0002-6842-1261
    Record's date: 2017-03-17
    Last page: 18741
    Journal volume: 22
    Papper version: info:eu-repo/semantics/acceptedVersion
    Link to the original source: http://onlinelibrary.wiley.com/doi/10.1002/chem.201604782/full
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Article's DOI: 10.1002/chem.201604782
    Entity: Universitat Rovira i Virgili
    Journal publication year: 2016
    First page: 18737
    Publication Type: Article Artículo Article
  • Keywords:

    Compostos carbonílics
    Alquens
    Catàlisi asimètrica
    gem-silyborylation
    Química
    Química
    Chemistry
    0947-6539
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