Articles producció científicaQuímica Física i Inorgànica

Opportune gem-Silylborylation of Carbonyl Compounds: A Modular and Stereocontrolled Entry to Tetrasubstituted Olefins

  • Identification data

    Identifier:  PC:2698
    Handle: https://hdl.handle.net/20.500.11797/PC2698
    Authors:  Fernández, E.; La Cascia, E.; Cuenca, A.B.
    Abstract:
    The stereocontrol on the synthesis of tetrasubstituted alkenes can be predicted by the use of gem-silaborated structures that perform selective silicon based or boron based cross-coupling reactions. Iododesilylation becomes a strategic issue to accomplish the target C-Si cross coupling. The easy access to gem-silaborated olefins, from ketones and HC(Bpin)2(SiMe3), is based on the strategic B-O olefination outcome.

  • Others:

    Link to the original source: http://onlinelibrary.wiley.com/doi/10.1002/chem.201604782/full
    Article's DOI: 10.1002/chem.201604782
    Journal publication year: 2016
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/acceptedVersion
    Record's date: 2017-03-17
    First page: 18737
    URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; La Cascia, E.; Cuenca, A.B.
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Article
    Last page: 18741
    ISSN: 0947-6539
    Author, as appears in the article.: Fernández, E. ; La Cascia, E.; Cuenca, A.B.
    Journal volume: 22
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Chemistry