Articles producció científicaQuímica Física i Inorgànica

Transition¿Metal¿Free Borylation of Allylic and Propargylic Alcohols

  • Identification data

    Identifier:  PC:3236
    Handle: https://hdl.handle.net/20.500.11797/PC3236
    Authors:  Fernández, E.; Miralles, N.; Alam, R.; Szabó, K.
    Abstract:
    The base-catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1-disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid-base adduct, [Hbase]+[MeO-B2pin2]- favoured the formation of 1,2,3-triborylated species from the tertiary allylic alcohols and 1-propargylic cyclohexanol, at 90ºC.

  • Others:

    Link to the original source: http://onlinelibrary.wiley.com/doi/10.1002/anie.201511255/abstract;jsessionid=3F8421836029BE6CE1432568D9FD2BEA.f01t04
    Article's DOI: 10.1002/anie.201511255
    Funding program: plan; Excelencia; CTQ2013-43395P
    Journal publication year: 2016
    Entity: Universitat Rovira i Virgili
    Paper version: info:eu-repo/semantics/publishedVersion
    Record's date: 2018-03-08
    First page: 4303
    URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Miralles, N. ; Alam, R. ; Szabó, K.
    Department: Química Física i Inorgànica
    Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
    Publication Type: Article
    Last page: 4307
    ISSN: 1433-7851
    Author, as appears in the article.: Fernández, E. ; Miralles, N. ; Alam, R. ; Szabó, K.
    licence for use: https://creativecommons.org/licenses/by/3.0/es/
    Journal volume: 55
    Research group: Organometàl.lics i Catàlisi Homogènia
    Thematic Areas: Chemistry

  • Keywords:

    allyl boronates
    allylic alcohols
    allylic borylation

  • Documents:

    DocumentPrincipal

  • Cerca a google

    Search to google scholar