Author, as appears in the article.: Fernández, E. ; Miralles, N. ; Alam, R. ; Szabó, K.
Department: Química Física i Inorgànica
URV's Author/s: FERNÁNDEZ GUTIÉRREZ, MARIA ELENA; Miralles, N. ; Alam, R. ; Szabó, K.
Keywords: allyl boronates allylic alcohols allylic borylation
Abstract: The base-catalyzed allylic borylation of tertiary allylic alcohols allows the synthesis of 1,1-disubstituted allyl boronates, in moderate to high yield. The unexpected tandem performance of the Lewis acid-base adduct, [Hbase]+[MeO-B2pin2]- favoured the formation of 1,2,3-triborylated species from the tertiary allylic alcohols and 1-propargylic cyclohexanol, at 90ºC.
Research group: Organometàl.lics i Catàlisi Homogènia
Thematic Areas: Química Química Chemistry
licence for use: https://creativecommons.org/licenses/by/3.0/es/
ISSN: 1433-7851
Author identifier: 0000-0001-9025-1791; 0000-0001-8598-0252; ;
Record's date: 2018-03-08
Last page: 4307
Journal volume: 55
Papper version: info:eu-repo/semantics/publishedVersion
Link to the original source: http://onlinelibrary.wiley.com/doi/10.1002/anie.201511255/abstract;jsessionid=3F8421836029BE6CE1432568D9FD2BEA.f01t04
Funding program: plan; Excelencia; CTQ2013-43395P
Licence document URL: https://repositori.urv.cat/ca/proteccio-de-dades/
Article's DOI: 10.1002/anie.201511255
Entity: Universitat Rovira i Virgili
Journal publication year: 2016
First page: 4303
Publication Type: Article Artículo Article
Repositori URV