Autor según el artículo: Fontanals, N.; Zohar, J.; Borrull, F.; Ronka, S.; Marce, R. M.;

Departamento: Química Analítica i Química Orgànica

Autor/es de la URV: Borrull Ballarín, Francesc / Fontanals Torroja, Núria / Marcé Recasens, Rosa Maria

Palabras clave: Weak cation-exchange interactions Weak cation-exchange interaction Water sampling Water pollutants, chemical Water pollutant Water analysis Wastewater Waste-water Waste water Temperature measurement Synthesis Sorption Sorbents Sorbent Solid-phase extraction Solid-phase Solid phasis Solid phase extraction Sewage effluent Scanning electron microscopy Resins Residues Process optimization Procedures Positive ions Polymers Physical parameters Physical chemistry Phase separation Pharmaceuticals Pharmaceutical preparations Mesoporous sorbent Mass-spectrometry Mass spectrometry Maleic acids Maleic acid derivative Maleic acid Maleates Liquid chromatography Isolation and purification Extraction Exchange character Environmental water samples Environmental samples Environmental sample Effluents Drugs Drug products Drug Divinylbenzene Controlled study Chromatography, liquid Chromatography Chemistry Chemical interaction Chemical analysis Cation exchanges Basic drugs Article

Resumen: This study presents a novel mixed-mode weak cation-exchange (WCX) material. This material was prepared by means of the functionalization of a mesoporous divinylbenzene (DVB) resin with maleic acid (maleic acid-DVB), which yielded a high carboxylic moiety content resulting in WCX interactions as well as suitable specific surface area for reversed-phase interactions. After the optimization of the solid-phase extraction (SPE) protocol to enhance the selectivity of the sorbent, this material was evaluated as a novel WCX sorbent in the SPE of a group of drugs from environmental water samples. The method is based on SPE followed by liquid chromatography (LC) coupled to high resolution mass spectrometry (HRMS) with an Orbitrap analyzer, and was validated and applied for the determination of basic drugs in river, effluent and influent wastewater samples. Maleic acid-DVB sorbent yielded suitable recovery rates (57% to 89%) and an acceptable matrix effect ( < 32%) thanks to the effective washing step included when these environmental waters were loaded through the novel resin. The method was applied to different environmental water samples and some basic drugs were suitably quantified in these environmental samples. (c) 2021 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ )

Áreas temáticas: Zootecnia / recursos pesqueiros Química Organic chemistry Nutrição Medicine (miscellaneous) Medicina veterinaria Medicina ii Medicina i Materiais Interdisciplinar Geociências General medicine Farmacia Engenharias ii Engenharias i Ciências biológicas iii Ciências biológicas ii Ciências biológicas i Ciências agrárias i Ciência de alimentos Chemistry, analytical Biotecnología Biodiversidade Biochemistry Biochemical research methods Analytical chemistry

Acceso a la licencia de uso: https://creativecommons.org/licenses/by/3.0/es/

Direcció de correo del autor: nuria.fontanals@urv.cat francesc.borrull@urv.cat rosamaria.marce@urv.cat nuria.fontanals@urv.cat

Identificador del autor: 0000-0002-7534-1964 0000-0003-2718-9336 0000-0002-5667-2899 0000-0002-7534-1964

Fecha de alta del registro: 2023-02-23

Volumen de revista: 1647

Versión del articulo depositado: info:eu-repo/semantics/publishedVersion

Enlace a la fuente original: https://www.sciencedirect.com/science/article/pii/S0021967321002892?via%3Dihub

URL Documento de licencia: http://repositori.urv.cat/ca/proteccio-de-dades/

Referencia al articulo segun fuente origial: Journal Of Chromatography a. 1647 (462165):

Referencia de l'ítem segons les normes APA: Fontanals, N.; Zohar, J.; Borrull, F.; Ronka, S.; Marce, R. M.; (2021). Development of a maleic acid-based material to selectively solid-phase extract basic compounds from environmental samples. Journal Of Chromatography a, 1647(462165), -. DOI: 10.1016/j.chroma.2021.462165

DOI del artículo: 10.1016/j.chroma.2021.462165

Entidad: Universitat Rovira i Virgili

Año de publicación de la revista: 2021

Tipo de publicación: Journal Publications